🔋 Strain‐Tolerant Layered Oxide Cathode for Sodium‐Ion Batteries Enabled by a Coherent Perovskite Phase
📝 فاز پروسکایتی همدوساخت در کاتد اکسید لایهای، کرنش شبکهای را در باتریهای سدیم-یون با نرخ بالا کاهش میدهد.
📚 Journal: Advanced Materials #AdvancedMaterials
📅 Date: 2026-10-05
🔬 Research Article
💡 Novelty & Significance:
The novelty lies in coherently intergrowing a perovskite Ca2MnO4 phase into layered NaNi1/3Fe1/3Mn1/3O2, creating an intrinsic strain-tolerant architecture. This perovskite buffer constrains lattice strain during rapid Na+ deintercalation, stabilizing structural evolution. It offers a structure-level strategy beyond compositional or surface tuning, enabling high-rate, long-life sodium-ion batteries.
🔗 10.1002/adma.75266
🏷 sodium-ion batteries · layered oxide cathode · strain tolerance · coherent perovskite phase · lattice strain
Post #14908
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