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📄 Cryptic Methylation Enables Amino-Maleimide Formation in Ligiamycin Biosynthesis

📝 متیلاسیون پنهان توسط LigM در بیوسنتز ligiamycin، واسطه methoxy-maleimide واکنش‌پذیر را برای تشکیل amino-maleimide از طریق افزایش-حذف غیرآنزیمی آماده می‌کند.

📚 Journal: Journal of the American
Chemical Society #JACS
📅 Date: 2026-10-07
🔬 Research Article
🔗 10.1021/jacs.6c15157

🏷 ligiamycin biosynthesis · amino-maleimide · cryptic methylation · PKS-NRPS · methoxy-maleimide
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