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📄 Selective B(4)–H Alkoxylation of o -Carboranes with Alcohols via Heteroleptic Cu(I)-Photocatalyzed 1,5-HAT-Enabled Boron Radical-Polar Crossover

📝 آلکوکسیل‌دار کردن انتخابی B(4)–H اورتو-کاربوران با الکل‌ها از طریق فتوکاتالیز Cu(I) و مسیر 1,5-HAT و جفت‌شدگی رادیکال-قطبی انجام می‌شود.

📚 Journal: Journal of the American
Chemical Society #JACS
📅 Date: 2026-10-02
🔬 Research Article
🔗 10.1021/jacs.6c16285

🏷 o-carborane · B–H alkoxylation · copper photocatalysis · 1,5-HAT · radical-polar crossover
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