Mendeleev Communications

Представляем третью часть статей 4 выпуска 2026 года!

Communications:
Synthesis and reactivity of octa(methoxycarbonyl)cycloheptatriene

Design and synthesis of spiro-linked azacycloalkane–dihydropyrano[4,3-d]pyrimidine compounds

Cycloaddition of 2-mercaptobenzaldehyde with 5-arylidene-2-thioxooxazolidin-4-ones

Three-component synthesis of new γ-piperidone-incorporating aza-14-crown-4 compounds

Lewis acid mediated rearrangements of spiro[2.n]alkane-1,1-dicarboxylates (n = 2–5): an experimental evidence of stepwise 1,2-zwitter-ion formation

The first example of α-ferrocenylalkylation of 2-thiohydantoin

Impact of structural features of halloysite nanotubes on adsorption and catalytic properties of β-galactosidase

Properties of submicron sized vaterite particles for incorporation of proteins

Modification of nanomagnetite surface with albumin: analysis by Hummel–Dreyer chromatography with Bradford detection of unbound protein

Electrochemistry of Pd-based nanoparticles prepared via thermal decomposition of palladium acetylacetonate

Hydrothermal synthesis of ultra-long copper nanowires and their application in the fabrication of supercapacitor electrodes

Chirality induction in atomically thin CdTe nanostructures

Comparative analysis of functional properties of the bimodal fluoride nanophosphors MGd0.7Eu0.3F4 (M = Na, K) and RbGd2.1Eu0.9F10

Представляем вторую часть статей 4 выпуска 2026 года!

Communications:
Electrochemical copolymerization-fabricated hybrid photosensitive layers based on poly-3,4-ethylenedioxythiophene and thiophene-substituted nickel porphyrinates

Improving the intrinsic photostability of MeNH3PbI3 layers by passivation with pentaerythritol tetrakis(2-mercaptoacetate)

The influence of synthesis and crystallization conditions on the structure and photoluminescent properties of {ZnLn} (Ln = Eu, Tb) complexes with benzoate anions

Octahedral terbium(III) cationic bis(alkoxide) complexes: synthesis, structural features and luminescence

Antenna effect in LnIII nitrates: the role of N-containing aromatic ligands in luminescence enhancement

Chromophore initiator as a tool for exploring ring-opening polymerization of cyclic oxalates

High-temperature lithium–polyimide batteries with a solvate complex of lithium bis(trifluoromethanesulfonyl)imide in tetraglyme as electrolyte

Catalytic alkylation of arenes employing synthesis gas with an in situ generated highly dispersed molybdenum disulfide catalyst

Copper-doped palladium and platinum catalysts for selective hydrogenation of diphenylacetylene

Adsorption-catalytic removal of diclofenac from water by a carbon-supported palladium catalyst

FeCl3/HCl-photocatalyzed synthesis of benzylidenebarbituric acids from methylarenes

Photochemical synthesis of benzo[d]imidazole-4-carboxylic acids from 3-(dialkylamino)-2-nitrobenzaldehydes

Опубликован 4 выпуск журнала за 2026 год:

— Выпуск 4

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Focus articles:

Porous liquids: current trends and investigation techniques

Communications:

Carboxymethylcellulose microgels with Bi3+ and Ru3+ for medical applications

Electrostatic and conformational analysis of piracetam and cyclo-L-prolylglycine to explain their potency difference

Molecular dynamics of deoxyhemoglobin complexes with the bis(μ-thiosulfato-S)bis(dinitrosylferrate)(2−) anion

Direct synthesis and cytotoxic activity of new macrodiolides with 2,5-disubstituted tetrahydrofuran moieties

Antitumor and antibacterial activity of novel menthyl- and bornyl-substituted 2-hydroxypropylphosphonium and arsonium salts

Redox-active salicylidenehydrazide analogues of vitamin E: synthesis, antioxidant and cytotoxic properties

Synthesis of novel antibiofilm kojic acid-based bis-pyridinium salts

Synthesis of phosphorus-containing proline analogs and assessment of their antitumor activity

Structure-based pharmacophore modeling and virtual screening using mono- and polyfunctional fragment bases

Impact of base matrix types on the properties of affinity chromatography resins with ligands based on staphylococcal protein A B-domain multimers

Molecularly imprinted β-cyclodextrin-based polymers for antibiotic recognition: synthesis and characterization

Представляем третью часть статей 3 выпуска 2026 года!

Communications:
Synthesis, structural features and cytotoxicity of new calix[4]resorcinols with methanesulfonate fragments

Design, synthesis and antitumor activity of new s-triazine–2-hydroxybenzophenone hybrids

Synthesis of oxo dihydro pyrrolo[1,2-a]quinazoline and benzo[e]pyrrolo[1,2-b][1,2,4]triazepine carboxylic acids

Fluorinated oxacalix[6]azacryptands: synthesis and complexation with propargyl alcohol

Synthesis of 4H-chromene-3-carbaldehydes via ring-opening of gem-dichlorocyclopropane-fused 4H-chromenes

Synthesis of secondary thiols from terminal alkenes and P2S5

Ultrafast microwave-assisted synthesis of nanosized HZSM-5 zeolite

Sodium vanadium fluorophosphate-based cathode material for anode-free sodium batteries with diglyme electrolyte

Chemically activated surface-assisted laser desorption/ionization mass spectrometry for detection of 8-hydroxyquinoline and its derivatives

Transfer hydrogenation co-processing of phenolic compounds and cyclohexanol

Highly efficient CuO/CeO2–SiO2 catalysts for the hydrogenation of nitrobenzene: new insights into cerium support

Polymer formulations for preventing wind and water erosion of saline soil

Представляем вторую часть статей 3 выпуска 2026 года!

Communications:

Synthesis and photophysical properties of carbazolyl-substituted flavones

Efficient green synthesis of the targeted proteolysis system component

Development and examination of self-assembled nanoformulation of biotinylated paclitaxel derivative

How to accelerate thermal poly(propylene carbonate) degradation?

Peculiarities of adsorption of nanocarriers on planar lipid surfaces

Self-healing ‘siloxane equilibrium’ materials after low-power electric breakdown in small-volume cells

3D printing with heat-curing hydrogels based on chitosan and β-glycerophosphate

Delivery of hydrophobic substances from an aqueous environment into polyesters using micelles

Formation of high-octane motor fuel via liquid phase alkylation promoted by new H2SO4–alkane Winsor III microemulsion systems

Methane hydrate growth on a graphene substrate

Photoinactivation of antibiotic-resistant Gram-negative bacteria using charged chlorin photosensitizers

An alternative synthesis of the antidepressant Navacaprant

Опубликован 3 выпуск журнала за 2026 год:

— Выпуск 3

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Focus articles:

Statistical methods in the NMR spectral analysis

Communications:

Overfitting in machine learning models for predicting partial atomic charges of drug-like molecules

Structural, electronic and vibrational properties of sulfated β–5 lignin model compounds: a DFT investigation

Quantum chemical investigation of the formation mechanism, structures and spectra of dibenzofuran excimer and dibenzofuran–fluorene exciplex

Structures and stability of small bimetallic In–Pd and Ag–Pd clusters: a DFT investigation

XPS and PM IRRAS study of chloromethane adsorption over Ag foil

Electrodeposited copper catalysts for the sustainable electrochemical reduction of nitrate to ammonia

Thermally activated (NHC)NiCp2 precatalysts for the cross-coupling of amines with aryl chlorides

Synthesis, structures and reactivity of Sc3+ and Y3+ bis(alkyl) complexes coordinated by [O,N,O] pincer amido ligand

Unexpected cyclization of the monoribbed-functionalized iron(II) clathrochelate into the macrobicyclic complex with six-membered N,S-fusing moiety

Zirconium-catalyzed cycloalumination of alkenes in a one-pot synthesis of 3-alkyl-1-(3-hydroxypropyl)cyclopentanols

Electrooxidative thiocyanation and halogenation of azopyrazoles

Hybrid polycomplexes of anionic alginate with a synthetic cationic polymer: attractive and poisonous for microorganisms

D. G. Sinelnikova🏛, O. A. Novoskoltseva🏛, N. G. Loiko🏛, Yu. A. Nikolaev🏛, A. A. Yaroslavov🏛

https://doi.org/10.1016/j.mencom.2024.01.010

Volume 34, issue 1, pages 31–33

7 Citations (Scopus 💻)

Negatively charged polycomplexes have been prepared by electrostatic complexation of synthetic cationic poly(diallyldimethylammonium chloride) with excess anionic sodium alginate. These polycomplexes exhibit pronounced antimicrobial activity due to the biodegradation of the alginate matrix and the release of the biocidal polycation. The results obtained are promising for the development of simultaneously attractive and toxic polymer constructs capable of destroying microorganisms.

#communication

Key features of perovskite solar cells operando stabilization with ionic liquid choline cinnamate

E. M. Nemygina🏛, N. N. Udalova🏛, E. I. Marchenko🏛, A. K. Moskalenko🏛, E. A. Goodilin🏛, A. B. Tarasov🏛

https://doi.org/10.1016/j.mencom.2024.09.011

Volume 34, issue 1, pages 31–33

7 Citations (Scopus 💻)

The ionic liquid choline cinnamate was applied for the first time as a defect passivator in light-absorbing layers of perovskite solar cells (PSCs). It was found that bulk passivation with an addition of 0.5% ionic liquid notably enhances the photothermal stability of PSCs, while surface passivation leads to the opposite effect with the loss of device stability, due to the complex origin of the influence of choline cinnamate on the defect structure and microstructure of hybrid halide perovskites.

#communication

Представляем третью часть статей 2 выпуска 2026 года!

Communications:

Process of complexation of lovastatin with transition metal ions (cobalt, gadolinium) explored by high resolution NMR spectroscopy and molecular dynamics

High-frequency electron spin resonance study of a single crystal of Egyptian blue at 4.2 K

In silico assessment of dielectric constants of magnetic composite sorbents for capillary electrochromatography

One-step synthesis of composite electrocatalyst of oxygen reduction reaction by electrochemical dispersion of PtCu alloy

Nickel–praseodymium catalysts supported on LaFeO3/SiO2 for ethanol steam reforming reaction

Palladium catalysts based on porous aromatic frameworks for hydrogenation of organic cyclic carbonates

Conversion of lignin-derived carboxylic acids into valuable chemicals under catalysis by in situ generated MoOx and WOx

Photocatalytic CO2 reduction over MXene/TiO2 under visible light: process conditions and stability aspects

Comparative study of methanol and dimethyl ether conversions to light olefins over a Mg–HZSM-5/Al2O3 catalyst in nitrogen and syngas atmospheres

Comparison of nonstoichiometric and Mg-containing calcium-deficient hydroxyapatites obtained by enzymatic synthesis

Mutual influence of surfactants and hydrophobic porphyrin on the processes of porphyrin disaggregation and micelle formation

Thermal ignition of a stoichiometric mixture of hydrogen and oxygen over nanoporous Ni, Co and Fe surfaces near the second ignition limit

An additive approach to the a priori determination of activation energies of thermoneutral reactions

Представляем вторую часть статей 2 выпуска 2026 года!

Communications:

Catalyst-free cyclization of DBU with α,β-ynones: substituent-controlled divergence

Molecular fan based on photoinduced recoordination in bis(aza-18-crown-6) cyclohexanone EtNH3+ complexes: mechanism and its unusual aspects

Synthesis and transformations of mesoionic imidazol-3-ium-4-olate carbaldehydes

4-(Propargylthio)sydnone imines: synthesis and reactivity in the azide–alkyne cycloaddition

Metal-free synthesis of 4-methylthio-3,4-dihydroisocoumarins from 2-(2-arylvinyl)benzoic acids

Synthesis of new [1,2,4]triazolo[5',1':2,3]pyrimido[4,5-b]indol-2-amines

Recyclization of exo-methylene bielectrophiles with 2-aminobenzimidazoles as an access to 3-substituted pyrimido[1,2-a]benzimidazol-2-ones

Radical change in the structure of Au25(SR)18 thiolate clusters after removal of bridging S*R groups from six (SR)Au(S*R)Au(SR) ‘staples’

A DFT insight into the properties of CrI3 fullerenes

New gold(I) complexes with fluorinated tricyclic NHC ligands: synthesis and catalytic activity

Facile synthesis of half-sandwich hydrido nickel complexes (NHC)Ni(H)(ƞ5-C5H5)

Tetranuclear nickel(II) complex with tetra-coordinated acetate and 1,3,5-tris(2-hydroxyphenyl)-2,4-diazapenta-1,4-diene ligands

Опубликован 2 выпуск журнала за 2026 год:

— Выпуск 2

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Focus articles:

Primary photophysical and photochemical processes in promising light-activated anticancer complexes of platinum, ruthenium and rhodium

Communications:

Chiral acyclic diaminocarbene complexes of palladium(II), platinum(II) and gold(I) from metal-mediated coupling of isocyanides with chiral amino acid amides

New abiraterone analogue with atypical position of N-heterocyclic substituent: synthesis, crystal structure and CYP17A1/CYP3A4 binding affinity

Efficiency of green-to-red chromophore conversion for AzamiGreen-derived fluorescent proteins

Bis-heterocyclic systems based on 1,2,4-triazole-3-carboxamide as new anti-SARS-CoV2 agents

Direct modification and antimicrobial activity of L-lysyl-L-leucine and its analogues

Concentration dependence of quadratic nonlinear-optical characteristics of azo-functionalized methacrylic copolymers

Production of medical radionuclide 44Sc from 44Ti by extraction with organophosphorus compounds

Safe, simple and efficient approach to bicyclic phosphines based on magnesium phosphide

Amberlyst-15 as a highly efficient and regenerative catalyst in the one-pot synthesis of areno[d][1,2]oxaphospholes

Photochemical synthesis of 3,4-dihydro-1-benzoxepine-2,5-diones from 2-formylaryl acrylates

Synthesis and antioxidant activity of apiol-derived 3-arylpropanamines

Nickel(II) complexes with novel nitron-type NHC ligands: synthesis and catalytic activity in the Suzuki–Miyaura coupling of aryl chlorides

A. S. Pyatachenko, A. Yu. Chernenko, S. B. Soliev, M. E. Minyaev🏛, V. M. Chernyshev

https://doi.org/10.1016/j.mencom.2024.01.012

Volume 34, issue 1, pages 39–42

8 Citations (Scopus 💻)

A new method has been developed for synthesizing nitron-type 1,4-dyaryl-3-arylamino-1,2,4-triazolium salts through a stepwise reaction of N,N'-diarylcarbodiimides with aryl hydrazines, trimethyl orthoformate and Me3SiCl. These salts have been utilized as NHC-proligands to prepare novel (NHC)2NiCl2 and (NHC)NiCpCl (Cp = cyclopentadienyl anion) complexes. Catalytic trials of these complexes uncovered a highly effective catalyst for the Suzuki–Miyaura cross-coupling of non-activated aryl chlorides.

#communication

Уважаемые коллеги!

Приглашаем Вас принять участие в работе научно-технологического конгресса «Химия и химические технологии в цифровую эпоху», который состоится 05-09 октября 2026 года в Институте органической химии им. Н.Д. Зелинского РАН (г. Москва). Председатель Научного комитета - акад. В. П. Анаников, председатель Организационного комитета - акад. А. О. Терентьев.
Подробная информация представлена на web-сайте конгресса https://ct2026.zioc.ru/, а также в телеграм-канале https://t.me/AI_and_science
Этот конгресс является уникальной площадкой, местом встречи фундаментальной химической науки, передовых инженерных решений и цифровых технологий. На конгрессе рассматриваются актуальные междисциплинарные темы, охватывающие передовые исследования в области химии, разработки в области химических технологий, цифровую химию и приложения искусственного интеллекта. Одним из важнейших результатов конгресса является формирование устойчивых связей представителей науки, технологических компаний и представителей высокотехнологической промышленности, которые будут успешно обмениваться опытом и объединят усилия для решения общих задач.

Тематический охват Конгресса включает в себя следующие направления:
1) Передовые исследования в области химии
2) Разработки в области химических технологий
3) Цифровая химия и приложения искусственного интеллекта

Направление Хим×Тех отражает современную логику развития: решающие прорывы возникают на пересечении химической науки и технологического развития, когда фундаментальные знания усиливаются инженерными методами, а технологии, в свою очередь, стимулируют появление новых научных идей.

По всем вопросам, связанным с процедурой регистрации и подачи тезисов, Вы можете обратиться в Организационный комитет конгресса:
Email: ct2026@ioc.ac.ru

Molecular structure–intrinsic photostability relationships for thiophene-benzothiadiazole alternating type conjugated polymers

P. M. Kuznetsov🏛, E. A. Komissarova🏛, S. A. Kuklin🏛🏛, P. A. Troshin🏛🇨🇳

https://doi.org/10.1016/j.mencom.2024.04.009

Volume 34, issue 3, pages 338–341

8 Citations (Scopus 💻)

A systematic study of the UV light-induced degradation of a series of structurally similar conjugated polymers revealed important relationships between the molecular structure of the used building blocks and photostability of the resulting materials. These findings form a set of important guidelines for future rational design of new absorber materials for efficient and stable organic solar cells.

#communication

Публикуем серию избранных статей 2024-2025 годов!

Synthesis, structure, and photoluminescent properties of a mixed carboxylate pentafluorobenzoate–phenylacetate complex of terbium

N. V. Gogoleva🏛, M. A. Shmelev🏛, A. S. Chistyakov🏛, G. A. Razgonyaeva🏛, V. M. Korshunov🏛, A. V. Tsorieva🏛, I. V. Taidakov🏛, A. A. Sidorov🏛, I. L. Eremenko🏛

https://doi.org/10.1016/j.mencom.2024.06.005

Volume 34, issue 4, pages 484–487

10 Citations (Scopus 💻)

A complex of mixed carboxylate pentafluorobenzoate (pfb) and phenylacetate (PhAc), viz. [Tb2(phen)2(pfb)2(PhAc)4] (phen is 1,10-phenanthroline), where each rare earth element (REE) ion is simultaneously coordinated to pentafluorobenzoic and phenylacetic acid anions, was for the first time synthesized and structurally characterized. To evaluate the influence of the second type of anion on the structure and photoluminescent properties, compounds with phenylacetic acid anions [Tb2(phen)2(PhAc)6] and pentafluorobenzoic acid anions [Tb2(EtOH)2(phen)2(pfb)6] were obtained. A change in the composition of the compounds from the phenylacetic acid anion to pentafluorobenzoate led to a change in the geometry of the metal scaffold and the REE polyhedron, a rearrangement of the system of non-covalent interactions according to the Hirshfeld surface analysis, and enhanced luminescence.

#communication

Коллеги, информируем, что все статьи 2025 года доступны к прочтению в открытом доступе!

Представляем третью часть публикаций 1 выпуска 2026 года!

Sodium intercalation into the NaNbTi(PO4)3 NASICON-type phosphate

Assessment of perovskite solar cells stability under continuous illumination via maximum power point tracking trends analysis

Synthesis and adsorption properties of Al–Zn and Al–Ni layered double hydroxides

Oxidation stability of solid-phase ZnS–Ag2S heteronanostructures

A novel method for the synthesis of hierarchical ZSM-5 zeolite in proton form

CO2 hydrogenation on catalysts based on Fe–Co double complex salts

Synthesis of carbon dioxide hydrate using lithium chloride solution and its thermochemical properties

Instability of thermoplastics as a key feature in catalyst preparation

Novel copolymers for fibers based on cyclocarbonates and lactide

Zinc complex as a source of highly labile non-shielded o-iminoquinone

Moving of the tetramethylbutanediyl substituent over the catecholcarbaldehyde core

Thixotropic properties of silica-based hydrogels

Представляем вторую часть публикаций 1 выпуска 2026 года!

2-Fluoroanthraquinone-catalyzed photooxidation of benzylic alcohols and aliphatic diols in supercritical carbon dioxide

Photoacid generation from substituted benzo[b]thiophene-2-carboxanilides

Photochemical synthesis of 3-trifluoromethyl-2,3-dihydrobenzofuran-3-ols

Low-temperature oxidation of volatile organic compounds by ozone on Mn-promoted W/Al2O3

Assembly of aldehydes and dimethylbarbituric acid into spirotricyclic furopyrimidines under the action of N-bromosuccinimide in water

Regioselective synthesis of novel derivatives of neo oxo carboxylic acids with two different functional groups from linear carboxylic acid chlorides

Synthesis of 2-sulfamoylquinoxaline 1,4-dioxide derivatives

Sulfonyl derivatives of 1,4-dihydropyrazolo[5,1-c][1,2,4]triazines in reactions with acyl/alkyl halides

Peculiarities of molecular interactions in the L-menthol–thymol system

New metal-free dye with an acceptor-anchor group of thieno[3,2-b]thiophene family for dye-sensitized solar cells

Novel multiresonant diindolophenazine fluorophore as a hole-transport organic semiconductor

Novel naphthalene benzimidazole-based materials for potassium metal batteries: revealing the importance of molecular weight for material performance

Lithium and potassium batteries using promising organic electrode material based on hexaazatrinaphthylene

Опубликован 1 выпуск журнала за 2026 год:

— Выпуск 1

Представляем первую часть вошедших публикаций!

Focus articles:

Design and biomedical applications of fluorescent probes based on hemicyanine dyes

Communications:

Substituted 3-aryl-4-nitroisoxazoles as potential blockers of the transport protein GLUT5: molecular design, synthesis and primary biotesting

Biomass-based enantioselective approach to 1,2-di(furan-2-yl)ethane-1,2-diamine and its derivatives

Synthesis of the linear octaarabinofuranoside related to the terminal fragment of mycobacterial polysaccharides

Coordination-driven self-assembly of pentacopper metallamacrocycles with N-(3-hydroxy-2-methyl-4-oxopyridin-1-yl)isonicotinamide units for antimycobacterial activity

Brightly emissive dinuclear silver(I) complexes based on a pyridine bisphosphine ligand

Metal carbonyl derivatives of CB6 and NB6 species: molecular rotors with hypercoordinated units

Monochloride complex of five-mercury anticrown [(CF3)2CHg]5 and reinvestigation of crystal structure of this anticrown

Synthesis and structure of bis(N-methylaza-15-crown-5)-fused 2,5‑dibenzylidenecyclopentanone and its novel bis-sandwich complex with Ba2+ ions

Influence of N-heterocyclic carbene modification on the catalytic performance of Pd clusters and nanoparticles in the Mizoroki–Heck reaction

C,N-Palladacycle based on N,N-dimethyl-N-(diphenylmethyl)amine as an effective phosphine-free (pre)catalyst for the Suzuki–Miyaura cross-coupling

Hydrogenation of diverse substrates over covalent triazine framework modified with copper

Modeling of enzyme-catalyzed P–O bond cleavage in the adenosine triphosphate molecule

M. G. Khrenova🏛🏛🏛, T. I. Mulashkina🏛, R. A. Stepanyuk🏛🏛🏛, A. V. Nemukhin🏛🏛

https://doi.org/10.1016/j.mencom.2024.01.001

Volume 34, issue 1, pages 1–7

7 Citations (Scopus 💻)

Recent achievements in molecular modeling of reaction mechanisms of the enzymatic ATP conversion to ADP or cAMP are discussed. Both of these reactions are initiated by the nucleophilic attack of an oxygen atom, but the P–O bridging bond cleavage occurs via different mechanisms, dissociative and associative. These mechanisms differ in the order of formation and cleavage of P–O bonds. For ATP ases, the dissociative mechanism is assumed, whereas ATP conversion to the cAMP occurs via associative mechanism. We suggest a novel approach based on the molecular dynamics simulations with combined quantum mechanics/molecular mechanics potentials of the enzyme–substrate complexes that can discriminate dissociative and associative reaction pathways by analysis of length distributions of the cleaving and forming P–O bonds.

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