🔋 Anion‐Driven Solvent Degradation Networks in High‐Concentration Battery Electrolytes
📝 شبکههای واکنش تخریب حلال القاشده توسط آنیون در الکترولیتهای پرغلظت باتری با کشف خودکار واکنش و مدلسازی میکروسینتیکی بررسی شد و مسیرهای تشکیل LiF و کربناتهای حلقویباز شناسایی شد.
📚 Journal: Advanced Energy Materials #AdvancedEnergyMaterials
📅 Date: 2026-10-15
🔬 Research Article | 🔓 Open Access | 📥 PDF
💡 Novelty & Significance:
This study maps anion-driven solvent degradation networks in high-concentration electrolytes using automated reaction discovery and microkinetic modeling, revealing how fluoride and fragments from LiFSI/LiTFSI drive solvent decomposition toward LiF and fluoro-organic species. It provides molecular-level rationale for unique SEI chemistries and suggests tuning anion-solvent interactions as a viable strategy for controlling interphase growth.
🔗 10.1002/aenm.71634
🏷 high-concentration electrolyte · solid electrolyte interphase · anion degradation · microkinetic modeling · LiFSI
Post #15313
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