🔋 Crystallography‐Dependent Plating/Stripping Kinetics and Interfacial Morphologies in Zn Metal Anodes
📝 جهتگیری بلوری، سینتیک آبکاری/جدایش و ریختشناسی سطحی آند Zn را کنترل کرده و وجه (002) عمر چرخهای طولانیتری در باتریهای Zn فراهم میکند.
📚 Journal: Angewandte Chemie International Edition #AngewandteChemie
📅 Date: 2026-10-14
🔬 Research Article | 🔓 Open Access | 📥 PDF
💡 Novelty & Significance:
This work uniquely quantifies facet-dependent Zn plating/stripping kinetics using scanning electrochemical cell microscopy, revealing j0(100) > j0(101) > j0(002). It establishes a kinetics–stability trade-off: despite slower charge transfer, the (002) facet yields longest cycling life and best full-cell retention. This links crystallographic control of charge transfer, dissolution topology, and reconstruction to durable Zn anode design.
🔗 10.1002/anie.1058773
🏷 Zn metal anode · crystallographic orientation · plating/stripping kinetics · interfacial morphology · SECCM
Post #15299
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