🔋 Radical Bearing Solid Electrolyte Interface as an Active Ionic Reservoir for Fast Li + Storage in Coordination Confined Fe@C Anodes
📝 آند Fe@C با محدودسازی کوئوردیناسیونی، ذخیرهسازی سریع Li+ را از طریق SEI پلیمری رادیکالدار به عنوان مخزن یونی فعال ممکن میسازد.
📚 Journal: Advanced Functional Materials #AdvancedFunctionalMaterials
📅 Date: 2026-10-13
🔬 Research Article
💡 Novelty & Significance:
The novelty lies in identifying a radical-bearing polymeric SEI that acts as an active ionic reservoir for space charge storage in Fe@C anodes. This links MOF-derived coordination confinement with Fe-catalyzed SEI reconstruction, enabling fast, strain-free Li+ storage (565 mAh g⁻¹ at 2C). It advances interfacial design by clarifying the SEI's ionic role, offering a pathway to durable, high-rate anodes.
🔗 10.1002/adfm.79050
🏷 Fe@C anode · solid electrolyte interphase · radical · Li+ storage · coordination confinement
Post #15215
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