🔋 Influence of arylene diimide linker aromaticity on the electrochemical performance of redox-active metal–organic framework cathodes for lithium-ion storage
📝 افزایش آروماتیسیته در لیگاندهای دیایمید آرایلن در MOFهای Zn-XDI باعث پایداری حالت کاهشیافته و بهبود ذخیرهسازی لیتیوم میشود.
📚 Journal: Journal of Materials Chemistry A #JMCA
📅 Date: Unknown
🔬 Research Article | 🔓 Open Access
💡 Novelty & Significance:
This study establishes linker aromaticity as a tunable design parameter for redox-active MOF cathodes, showing that PMDI, NDI, and PDI linkers in isoreticular Zn-XDI MOFs progressively stabilize reduced states and boost Li-ion storage. Zn-PDI and Zn-NDI achieve excellent cycling stability, offering a new strategy for engineering high-performance organic electrode materials.
🔗 10.1039/d6ta05048d
🏷 metal-organic framework · arylene diimide · lithium-ion storage · aromaticity · cathode
Post #15187
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