🔋 An electrolyte-versatile π–d conjugated coordination polymer cathode with multiple active sites for durable rechargeable aluminum batteries
📝 این مقاله یک کاتد پلیمر کوئوردیناسیون مزدوج π-d را برای باتریهای آلومینیومی قابل شارژ معرفی میکند که چرخهپذیری طولانی و ظرفیت بالا دارد.
📚 Journal: Journal of Materials Chemistry A #JMCA
📅 Date: Unknown
🔬 Research Article
💡 Novelty & Significance:
The novelty lies in a 3D π–d conjugated Fe₂(DHBQ)₃ cathode enabling electron delocalization, suppressed dissolution, and synergistic AlCl₂⁺ binding, Fe redox, and EMIm⁺ π-interactions. Its significance is exceptional durability—110.7 mAh g⁻¹ over 40,000 cycles at 2 A g⁻¹—and electrolyte versatility, supporting low-cost molten-salt electrolytes for practical rechargeable aluminum batteries.
🔗 10.1039/d6ta06073k
🏷 aluminum battery · conjugated coordination polymer · cathode · multiple active sites · molten-salt electrolyte
Post #15007
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