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Post #14973 2
🔋 A Universal Class of Cubic Crystalline Alkali Organic–Inorganic Glyme-Based Halides

📝 خانواده‌ای جهانی از هالیدهای قلیایی-گلایم با ساختار مکعبی CsClمانند ساخته شد؛ رسانایی یونی جامد پایین اما در حالت مایع 1–10 mS/cm است و در سلول‌های پتاسیم‌یون واکنش جابه‌جایی/درج رخ می‌دهد.

📚 Journal: Journal of the American
Chemical Society #JACS
📅 Date: 2026-10-07
🔬 Research Article

💡 Novelty & Significance:
This work introduces a universal self-assembly route to cubic alkali glyme-based halides (ABX6·mGn), a new crystalline family with CsCl-like structures. It reveals SSIP-to-CIP transformations, tunable ionic conductivity, and KTaCl6 electrochemical reactivity forming K2TaCl6. These findings expand glyme-halide coordination chemistry, offering a versatile platform for solid-state ionics and battery applications.

🔗 10.1021/jacs.6c14058

🏷 glyme halides · solid electrolyte · potassium-ion battery · ionic conductivity · self-assembly
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