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Post #14786 51
🔋 Demarcating the Effects of Aliphatic Ester Chain Lengths and Molecular Weight on Electrode–Electrolyte Interphase Formation for Wide-Temperature Operation of Lithium-Ion Batteries

📝 اثر طول زنجیره استرهای آلیفاتیک بر تشکیل لایه بین‌سطحی الکترود-الکترولیت و عملکرد باتری لیتیوم-یون در دمای گسترده ۶۰- تا ۶۰+ درجه سانتی‌گراد بررسی شد.

📚 Journal: Journal of the American
Chemical Society #JACS
📅 Date: 2026-10-02
🔬 Research Article

💡 Novelty & Significance:
This work reveals how aliphatic ester alkyl/alkoxy chain lengths govern electrolyte solvation, decomposition, and interphase formation in LIBs. It enables wide-temperature operation (−60 to +60 °C) via chain engineering, achieving 110 mAh g⁻¹ at −60 °C, and establishes a structure–property framework for designing tuned ester electrolytes, advancing wide-temperature battery performance.

🔗 10.1021/jacs.6c10537

🏷 lithium-ion battery · electrolyte · aliphatic ester · interphase · wide-temperature
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